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Air Emission Event Report Database Incident 341135

Incident Tracking Number: 341135 Incident Status: CLOSED
Report Type: FINAL Report Date: 09/11/2020
Name of Owner or Operator: MOTIVA CHEMICALS LLC CN: CN603743030
Regulated Entity Name: MOTIVA CHEMICALS RN: RN100217389
Physical Location: 4241 SAVANNAH AVE; PORT ARTHUR, TX 77640
County: JEFFERSON
Event/Activity Type: AIR SHUTDOWN
Date and Time Event Discovered or Scheduled Activity Start: 08/25/2020 07:05 AM
Date and Time Event or Scheduled Activity Ended: 09/02/2020 07:38 AM
Event Duration: 192 hours, 33 minutes
Process Unit or Area Common Names
Light Olefins Unit (LOU)
Facility Common Name Facility Identification Number (FIN)
LOU Flare LOUFLARE
1 - Emission Point Common Name: Emission Point Number:
LOU Flare LOUFLARE
List of Air Contaminant Compounds - 16 total
Description Est. Quantity/
Opacity
Units Emission
Limit
Units Authorization
1,3-BUTADIENE 44.35 POUNDS 0.0   No specific Authorization
Benzene 220.36 POUNDS 0.0   No specific Authorization
Butanes 948.97 POUNDS 0.0   No specific Authorization
Butenes, All Isomers 90.03 POUNDS 0.0   No specific Authorization
Carbon Monoxide 17056.76 POUNDS 0.0   No specific Authorization
Ethylbenzene 3.68 POUNDS 0.0   No specific Authorization
Ethylene (gaseous) 7447.21 POUNDS 0.0   No specific Authorization
Isobutane 82.51 POUNDS 0.0   No specific Authorization
Isobutylene 176.91 POUNDS 0.0   No specific Authorization
Nitrogen dioxide 134.53 POUNDS 0.0   No specific Authorization
Nitrogen oxide 2556.02 POUNDS 0.0   No specific Authorization
Pentanes 4.05 POUNDS 0.0   No specific Authorization
Propane 3136.85 POUNDS 0.0   No specific Authorization
Propylene 16037.12 POUNDS 0.0   No specific Authorization
Toluene 54.29 POUNDS 0.0   No specific Authorization
Xylenes 3.14 POUNDS 0.0   No specific Authorization
Cause of Emission Event or Excess Opacity Event, or Reason for Scheduled Activity:
Motiva Chemicals LLC (RN100217389; TCEQ Account JE0135Q) Port Arthur Chemicals (PAC) facility began shutting down operations of its process units, on August 25, 2020 at 07:05 hours in preparation for Hurricane Laura to ensure the plant was brought down safely and with minimal environmental impacts. Emissions during the shutdown event were routed to the Light Olefins Unit (LOU) Flare for destruction.
Actions Taken, or Being Taken, to Minimize Emissions And/or Correct the Situation:
Shutdown activities were performed per appropriate shutdown procedures. To minimize emissions, the LOU was brought down in a safe and controlled manner. Excess emissions generated were routed to the LOU Flare for destruction.
Basis Used to Determine Quantities and Any Additional Information Necessary to Evaluate the Event:
Emissions are based on engineering estimates and judgment, stream speciation, estimated duration, and engineering calculations. Emissions of benzene, 1,3-butadiene, and oxides of nitrogen are estimated to have exceeded state and federal reportable quantities (RQs) over a 24-hour period. Emissions of ethylene, propylene, and carbon monoxide are estimated to have exceeded state RQs over a 24-hour period. It was also observed that during this incident, the LOU flare smoked intermittently. Note that at the time of the Initial State of Texas Environmental Electronic Reporting System (STEERS) Report, formal emissions estimates were not available. PAC stated in the report that, “All amounts released listed in this report are preliminary estimates of the potential emissions based on current available information. These estimates may or may not be indicative of the actual amounts or compounds released. It is likely that better emissions estimates will be provided in the Final State of Texas Environmental Electronic Reporting System (STEERS) Report. The dates/times given in this report are only estimates. The duration of this shutdown event may vary significantly from this estimate. The actual shutdown event duration will be provided in the Final STEERS Report.” Based on information presently known to PAC the shutdown activity began on August 25, 2020 at approximately 07:05 hours and ended on September 2, 2020 at approximately 07:38 hours. For the purpose of this report the duration is 192 hours and 33 minutes. The initial notification was not filed more than 10 days prior to the planned maintenance activity; however, PAC filled the notice as soon as practicable, in accordance with 30 TAC §101.211(a). In accordance with applicable regulations and guidelines, the National Response Center (NRC), Texas State Emergency Response Commission (SERC), and the Local Emergency Planning Commission (LEPC) were notified. NRC# 1285525 - 08/25/2020 0813; Rawls SERC# 20202720 - 08/25/2020 0814; Weckerle
Initial Notification Date/Time: 08/24/2020 10:44 AM Method: STEERS
Notification Jurisdictions: REGION 10 - BEAUMONT
Publication Status: VERIFIED BY A CUSTOMER
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